IJEP 44(14): 1254-1259 : Vol. 44 Issue. 14 (Conference 2024)
Noman Ahmed Siddiqui and Priya Saxena*
Parul University, Department of Civil Engineering, Parul Institute of Technology, Vadodara – 391 760, Gujarat, India
Abstract
This study presents the green synthesis and application of nanoscale zero-valent iron (nZVI) supported on activated carbon (AC) for the removal of reactive dyes from aqueous solutions. The synthesis process involved the preparation of nZVI through the extraction of Rosa indica petals followed by loading onto activated carbon. Fourier transform infrared spectroscopy (FTIR) analysis revealed the presence of functional groups indicative of the synthesized nZVI sample. The efficiency of the synthesized AC-nZVI composite in decolourizing Methylene Blue (MB) dye was evaluated across various concentrations ranging from 5-50 ppm. The results demonstrated a significant enhancement in decolourization efficiency with AC-nZVI compared to nZVI alone. At concentrations of 5 ppm, AC-nZVI achieved a degradation efficiency of 97.87% compared to 79.46% for nZVI alone. This trend persisted across all concentrations tested, with AC-nZVI consistently outperforming nZVI. The superior performance of AC-nZVI can be attributed to the synergistic effects between the activated carbon support and the nano zero-valent iron particles, offering promising prospects for efficient and sustainable water remediation technologies.
Keywords
Activated carbon, Nanoscale zero-valent iron (nZVI), Methylene Blue, Fourier transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM)
References
- Heidarizad, M. and S.S. Sengör. 2016. Synthesis of graphene oxide/magnesium oxide nanocom-posites with high-rate adsorption of Methylene Blue. J. Molec. Liquids. 224: 607–617. DOI: 10.10 16/j.molliq.2016.09.049.
- Yagub, M.T., et al. 2014. Dye and its removal from aqueous solution by adsorption: A review. Adv. Colloid Interface Sci., 209: 172–184. DOI: 10.101 6/j.cis.2014.04.002.
- Gupta, V. K. and S. Suhas. 2009. Application of low-cost adsorbents for dye removal – A review. J. Env. Manage., 90(8): 2313–2342. DOI: 10.101 6/j.jenvman.2008.11.017.
- Raman, C.D. and S. Kanmani. 2016. Textile dye degradation using nano zero valent iron: A review. J. Env. Manage., 177: 341–355. DOI: 10.1016/j.jenvman.2016.04.034.
- Sohrabi, M. R., et al. 2015. Removal of diazo dye Direct Red 23 from aqueous solution using zero-valent iron nanoparticles immobilized on multi-walled carbon nanotubes. Water Sci. Tech., 71(9): 1367–1374. DOI: 10.2166/wst.2015.106.
- Ghaedi, M., et al. 2015. Efficient adsorption of Europhtal onto activated carbon modified with ligands (1E,2E)-1,2-bis(pyridin-4-ylmethylene)hy-drazine (M) and (1E,2E)-1,2-bis(pyridin-3-ylmethy-lene) hydrazine (SCH-4); response surface methodology. RSC Adv., 5(53): 42376–42387. DOI: 10.1039/c5ra03622d.
- Suganya, S. and P. Kumar. 2018. Kinetic and thermodynamic analysis for the redemption of effluents containing Solochrome Black T onto powdered activated carbon: A validation of new solid-liquid phase equilibrium model. J. Molec. Liquids. 259: 88–101. DOI: 10.1016/j.molliq.2018.03.004.
- Kumar, P.S., et al. 2011. Adsorption of Methylene Blue dye from aqueous solution by agricultural waste: Equilibrium, thermodynamics, kinetics, mechanism and process design. Colloid J., 73(5): 651–661. DOI: 10.1134/s1061933x11050061.
- Kumar, P.S., et al. 2013. Adsorption of basic dye onto raw and surface modified agricultural waste. Env. Progress Sustain. Energy. 33(1): 87–98. DOI: 10.1002/ep.11756.
- Manikandan, G., P.S. Kumar and A. Saravanan. 2018. Modelling and analysis on the removal of Methylene Blue dye from aqueous solution using physically/chemically modified Ceiba pentandra seeds. J. Ind. Eng. Chem., 62: 446–461. DOI: 10.1016/j.jiec.2018.01.028.
- Satapanajaru, T., et al. 2011. Enhancing decolouri-zation of Reactive Black 5 and Reactive Red 198 during nano zerovalent iron treatment. Desalination. 266(1–3): 218–230. DOI: 10.1016/j.desal.20 10.08.030.
- Zhang, Q., et al. 2021. Active biochar support nano zero-valent iron for efficient removal of U(VI) from sewage water. J. Alloys Compounds. 852: 156993. DOI: 10.1016/j.jallcom.2020.156993.
- Shu, H., et al. 2010. Using resin supported nano zero-valent iron particles for decolouration of Acid Blue 113 azo dye solution. J. Hazard. Mater., 184 (1–3): 499–505. DOI: 10.1016/j.jhazmat.2010. 08.064.
- Shu, H., M. Chang and C. Chang. 2009. Integration of nanosized zero-valent iron particles addition with UV/H2O2process for purification of azo dye Acid Black 24 solution. J. Hazard. Mater., 167(1–3): 1178–1184. DOI: 10.1016/j.jhazmat. 2009.01.106.
- Shu, H., et al. 2007. Reduction of an azo dye Acid Black 24 solution using synthesized nanoscale zero valent iron particles. J. Colloid Interf. Sci., 314(1): 89–97. DOI: 10.1016/j.jcis.2007.04.071.
- Bokare, A.D., et al. 2008. Iron-nickel bimetallic nanoparticles for reductive degradation of azo dye Orange G in aqueous solution. Appl. Catalysis B Env., 79(3): 270–278. DOI: 10.1016/j.apcatb. 2007.10.033.
- Han, L., et al. 2015. Biochar supported nanoscale iron particles for the efficient removal of Methyl Orange dye in aqueous solutions. PLOS One. 10(7): e0132067. DOI: 10.1371/journal.pone.0132067.
- Abdelfatah, A.M., et al. 2021b. Green synthesis of nano-zero-valent iron using Ricinus communis seeds extract: Characterization and application in the treatment of Methylene Blue-polluted water. ACS Omega. 6(39): 25397–25411. DOI: 10.1021/acsomega.1c03355.
- Rashtbari, Y., et al. 2022. Green synthesis of zero-valent iron nanoparticles and loading effect on activated carbon for furfural adsorption. Chemosphere. 287: 132114. DOI: 10.1016/j.chemo-sphere.2021.132114.
- Ghaedi, M., et al. 2012b. Comparison of silver and palladium nanoparticles loaded on activated carbon for efficient removal of Methylene Blue: Kinetic and isotherm study of removal process. Powder Tech., 228: 18–25. DOI: 10.1016/j.powtec. 2012.04.030
- Salama, W., M.E. Aref and R. Gaupp. 2015. Spectroscopic characterization of iron ores formed in different geological environments using FTIR, XPS, Mössbauer spectroscopy and thermoanalyses. Spectrochimica Acta Part A: Molec. Biomolec. Spectroscopy. 136: 1816–1826. DOI: 10.1016/j.saa.2014.10.090.
- Parikh, S.J. and J. Chorover. 2006. ATR-FTIR spectroscopy reveals bond formation during bacterial adhesion to iron oxide. Langmuir. 22(20): 8492–8500. DOI: 10.1021/la061359p.
- He, Y., et al. 2012. The comparative study on the rapid decolourization of azo, anthraquinone and triphenylmethane dyes by zero-valent iron. Chem. Eng. J., 179: 8–18. DOI: 10.1016/j.cej.2011. 05.107.