Feasibility Studies on the Removal of Rose Bengal Dye through Electrolytic Degradation

IJEP 42(10): 1178-1185 : Vol. 42 Issue. 10 (October 2022)

Aswin Sriram1* and Anish Nair2

1. Sri Sivasubramaniya Nadar College of Engineering, Department of Civil Engineering, Kalavakkam – 603 110, Tamil Nadu, India
2. Kalasalingam Academy of Research and Education, Department of Mechanical Engineering, Krishnankoil – 626 126, Tamil Nadu, India

Abstract

Removal of colour during the treatment of wastewater has always urged the scientific community to create sustainable, cost-saving and novel methods in recent times. The present study aims to study the feasibility of the removal of Rose Bengal dye from an aqueous solution through an electrolytic oxidation reaction. Zinc and carbon cathodes are placed in an electrolytic solution containing Fenton’s reagent and Rose Bengal dye ranging from concentrations of 4 to 12 ppm. The operational parameters like voltage (4.8 V, 6 V and 7.2 V), catalyst concentration (0.18 mM, 0.27 mM and 0.36 mM) and electrode selection were varied to determine the maximum removal efficiency. The combination of 4.8 V – 0.36 mM – 4 ppm presented a maximum removal efficiency of 92.97% for zinc electrode while the combination of 7.2 V – 0.36 mM – 4 ppm showed maximum removal of 94.99% for carbon electrode in Rose Bengal removal from aqueous solution. The results from the laboratory studies were interpreted with a variance analysis through ANOVA and regression equations with a desirability factor of more than 94% were obtained.      

Keywords

Rose Bengal, Advanced oxidation, Electro-Fenton, ANOVA, Genetic algorithm

References

  1. Sriram, A. and G. Swaminathan. 2018. Removal of Rose Bengal dye from aqueous solutions using chitosan coated activated carbon prepared from Prosopis juliflora. Indian J. Env. Prot., 38(10):827–835.
  2. Gupta, V.K., et al. 2012. Batch and bulk removal of hazardous colouring agent Rose Bengal by adsorption techniques using bottom ash as adsorbent. RSC Adv., 2(22):8381–8389.
  3. Naushad, M., et al. 2016. Adsorption of Rose Bengal dye from aqueous solution by amberlite Ira-938 resin: Kinetics, isotherms and thermodynamic studies. Desalin. Water Treat., 57(29):13527–13533.
  4. Kooh, M.R.R., et al. 2016. Separation of toxic Rhodamine B from aqueous solution using an efficient low-cost material, Azolla pinnata, by adsorption method. Env. Monit. Assess., 188(2):1–15.
  5. Clematis, D. and M. Panizza. 2021. Electro-Fenton, solar photoelectro-Fenton and UVA photoelectro-Fenton: Degradation of Erythrosine B dye solution. Chemosphere. 270:129480.
  6. Es’haghzade, Z., et al. 2017. Facile synthesis of Fe3O4 nanoparticles via aqueous based electro chemical route for heterogeneous electro-Fenton removal of azo dyes. J. Taiwan Inst. Chem. Eng., 71:91–105.
  7. Li, X., et al. 2017. Novel bio-electro-Fenton technology for azo dye wastewater treatment using microbial reverse-electrodialysis electrolysis cell. Bioresour. Tech., 228:322–329.
  8. Oturan, N. and M.A. Oturan. 2018. Electro-Fenton process: Background, new developments and applications (chapter 8). Electrochem. Water Wastewater Treat., 193–221.
  9. Le, T.X.H., et al. 2016. Toxicity removal assessments related to degradation pathways of azo dyes: Toward an optimization of electro-Fenton treatment. Chemosphere. 161:308–318.
  10. Largitte, L. and R. Pasquier. 2016. A review of the kinetics adsorption models and their application to the adsorption of lead by an activated carbon. Chem. Eng. Res. Des., 109:495–504.
  11. Li, X. and Y. Li. 2019. Adsorptive removal of dyes from aqueous solution by KMnO4modified rice husk and rice straw. J. Chem., 2019(4):1-9.
  12. Brillas, E., et al. 2009. Electro-Fenton process and related electrochemical technologies based on Fenton’s reaction chemistry. Chem. Rev., 109(12): 6570–6631.
  13. Divyapriya, G. and P.V. Nidheesh. 2020. Importance of graphene in the electro-Fenton process. ACS Omega. 5(10):4725–4732.
  14. Central, O.O.F. 2020. Application of pineapple leaves as adsorbents for removal of Rose Bengal from wastewater: Process composite design (FCCCD ). Molecules. 25(16):3752.
  15. Chen, Y.D., et al. 2018. Highly efficient adsorption of dyes by biochar derived from pigments-extracted macroalgae pyrolyzed at different temperature. Bioresour. Tech., 259(2):104–110.