Application of Response Surface Methodology for the Treatment of Dairy Wastewater by Electro-Fenton Process

IJEP 43(2): 119-126 : Vol. 43 Issue. 2 (February 2023)

R. Lavanya and Rashma Shetty*

University BDT College of Engineering, Department of Civil Engineering, Davangere – 577 004, Karnataka, India

Abstract

In this research, the treatment of dairy industry effluent by electro-Fenton process using aluminium plate electrodes for the removal of parameters, such as chemical oxygen demand (COD) and total suspended solids (TSS) were studied. The experimental design and optimization of independent variables, such as Fenton dosage (x1), electrolysis time (x2) and electric current (x3) were evaluated by means of Box-Behnken design (BBD) in response surface methodology (RSM). The second-order quadratic model was utilized for the prediction of removal percentage of COD and TSS in several operational conditions. The true impact of each independent variable and relationship between dependent and independent variables was analyzed by using analysis of variance (ANOVA). The treatment efficiency of electro-Fenton (E-F) process for the removal of TSS and COD was studied by varying the independent variables, such as Fenton dosage (0.01-0.02) mol/L, electrolysis time (20-40 min) and electric current (2-4 A). The optimal conditions of independent variables for maximum removal efficiencies of responses are Fenton dosage of 0.015 mol/L, electric current of 3A and electrolysis time of 40 min. The maximum removals of COD and TSS at optimized conditions are found to be 86.19% and 91.75%, respectively.

Keywords

Electro-Fenton, Response surface methodology, Box-Behnken design, Analysis of variance, Chemical oxygen demand, Total suspended solids

References

  1. Sankar, G.P., 2007. Studies on treatment of low-strength effluents by UASB reactor and its application to dairy industry wash waters. Indian J. Biotech., 6(2):234-238.
  2. Ramesh, T., V. Nehru Kumar and G. Srinivasan. 2012. Kinetic evaluation of fixed film fixed bed anaerobic reactor by using dairy wastewater. Int. J. Pharm. Biol. Archives. 3(4):835-837.
  3. Deshannavar, U.B., R.K. Basavaraj and N.M. Naik. 2012. High rate digestion of dairy industry effluent by upflow anaerobic fixed-bed reactor. J. Chem. Pharm. Res., 4(6):2895-2899.
  4. Shete, B. S. and N.P. Shinkar. 2013. A review on dairy wastewater characteristics, sources and its environmental effects. Int. J. Curr. Eng. Tech., 3:1611-1615.
  5. Kushwaha, J.P., I.D. Mall and V.C. Srivastava. 2011. A study on several technologies available for the dairy effluent treatment. Sep. Purif. Tech., 76(2):198-205.
  6. Vourch, M., et al. 2008. Treatment of dairy industry wastewater by reverse osmosis for water reuse. Desalination. 219:190-202.
  7. Ramasamy, E.V., et al. 2004. Feasibility studies on the treatment of dairy wastewater with upflow anaerobic sludge blanket reactors. Bioresour. Tech., 93(2):209-212.
  8. Bruguera-Casamada, Carmina, et al. 2018. Advantages of electro-Fenton over electrocoagulation for disinfection of dairy wastewater. Chem. Eng. J., DOI:10.1016/j.cej.2018.09.136.
  9. Farizoglu, B. and S. Uzumer. 2011. The investigation of dairy industry wastewater treatment in a biological high performance membrane system. Biochem. Eng. J., 57:46-54.
  10. Praneeth, K., et al. 2014. Performance assessment and hydrodynamic analysis of a submerged membrane bioreactor for treating dairy industrial effluent. J. Hazard. Mater., 274:300-313.
  11. Baskaran, K., J.M. Palmowski and B.M. Watson. 2000. Wastewater reuse and treatment options fort be dairy industry. Water Sci. Tech., 3:85-91.
  12. Sengin, I.A. and M. Ozacar. 2006. Treatment of dairy wastewater by electrocoagulation using mild steel electrodes. J. Hazard. Mater., B137:1197-1205.
  13. Banu, J.R., et al. 2008. Treatment of diary wastewater using anaerobic and solar photocatalytic methods. Solar Energy. 82(9):812-819.
  14. Raghunath, B.V., et al. 2016. Study of the effects of dairy effluent on environment-A review. Env. Sci. Eng., 239-249.
  15. Perle, M., S. Kimchie and G. Shelef. 1995. Some biochemical aspect of anaerobic degradation of dairy wastewater. Water Res., 29(6):1549-1554.
  16. Deshpande, D.P., J.J. Patil and S.V. Anekar. 2012. Biomethanation of dairy waste. Res. J. Chem. Sci., 2(4):35-39.
  17. Wheatley, A. 1990. Anaerobic digestion : A waste treatment technology. Elsevier Applied Science, London and New York.
  18. Kushwaha, J.P., V.C. Srivastava and I.D. Mall. 2010a. Treatment of dairy wastewater by inorganic coagulants : Parametric and disposal studies. Water Res., 44:5867-5874.
  19. Chen, Z., et al. 2018. Physico-chemical characterization of tight nanofiltration membranes for dairy wastewater treatment. J. Membr. Sci., 547:51-63.
  20. Akansha, J., et al. 2020. Treatment of dairy industry wastewater by combined aerated electrocoagulation and phytoremediation process. Chemosphere. 253:126652. DOI:10.1016/j.chemosphere 2020.126652.
  21. Sengila, A. and M. Ozacar. 2006. Treatment of dairy wastewaters by electrocoagulation using mild steel electrodes. J. Hazard. Mater., 137(2): 1197-1205.
  22. Hamdan de Andrade, L., et al. 2014. Nanofiltration as tertiary treatment for the reuse of dairy wastewater treated by membrane bioreactor. Sep. Purif. Tech., 126:21–29.
  23. Akkaya, G.K., et al. 2018. Modelling and optimizing Fenton and electro-Fenton process for dairy wastewater treatment using response surface methodology. Int. J. Env. Sci., Tech., 16(5):2343-2358.
  24. Yavuz, Y., et al. 2011. Treatment of dairy industry wastewater by EC and EF processes using hybrid Fe-Al plate electrodes. J. Chem. Tech. Biotech., 86:964-969.
  25. Davarnejad, Reza and Mehrazin Nikseresht. 2016. Dairy wastewater treatment using an electrochemical method : Experimental and statistical study. J. Electroanal. Chem., 775:364-373.
  26. Davarnejad, Reja, Mehrazin Nikseresht and Iman Ajkdeh. 2017. An efficient technique for dairy wastewater treatment. Int. J. Dairy Tech., DOI: 10.1111/1471-0307.12475.
  27. Casado, J., J. Fornaguera and M.I. Galan. 2006. Pilot scale mineralization of organic acids by electro-Fenton process plus sunlight exposure. Water Res., 40:2511-2516.
  28. Aval, A.E., et al. 2017. Removal of landfill leachate’s organic load by modified electro-Fenton process. Int. J. Electrochem. Sci.
  29. Li, W., Q. Zhou and T. Hua. 2010. Removal of organic matter from landfill leachate by advanced oxidation processes : A review. Int. J. Chem. Eng., 2010:1-10.
  30. IS 3025-1. 1987. Methods of sampling and test (physical and chemical) for water and wastewater. Part 1 – Sampling. Bureau of Indian Standards, New Delhi.
  31. Engineering statistics handbook. Thesis of Box Behnken design. Available at : www.itl.nist.gov.
  32. Khuri, a.I. and S. Mukhopadhyay. 2010. Response surface methodology. Wiley Interdisciplinary Reviews : Computational Statistic. 2:128-149.
  33. Lopez, A., et al. 2004. Fenton’s pre-treatment of mature landfill leachate. Chemosphere. 54(7): 1005-1010.
  34. Mohajeri, S., et al. 2019. Landfill leachate treatment through electro-Fenton oxidation. Poll., 5(1):199-209. DOI:10.22059/poll.2018. 249210. 364.
  35. Korbahti, B.K. and A. Tanyolac. 2008. Electrochemical treatment of simulated textile wastewater with industrial components and Levafix Blue CA reactive dye : Optimization through response surface methodology. J. Hazard. Mater., 151(2-3):422-431.
  36. Zhang, H., et al. 2007. Degradation of 4-nitrophenol in aqueous medium by electro-Fenton method. J. Hazard. Mater., 145:227-232.
  37. Mohajeri, S., et al. 2010. Statistical optimization of process parameters for landfill leachate treatment using electro-Fenton technique. J. Hazard. Mater., 176:749-758.
  38. Bazrafshan, E., et al. 2013. Application of electrocoagulation process for dairy wastewater treatment. J. Chem. DOI:10.1155/2013/640139.
  39. Tehamango, S., et al. 2010. Treatment of dairy effluents by electrocoagulation using aluminium electrodes. Sci. Total Env., 408:947-952.