A descriptive study of hydrochar prepared from Seasame Oilcake and Groundnut Oilcake- an eco-friendly approach

IJEP 44(3): 195-205 : Vol. 44 Issue. 3 (March 2024)

S. Elanchimuthu1, C. Dhivya1*, S. Manimegalai2 and A. Prithiba1*

1. Avinashilingam Institute for Home Science and Higher Education for Women, Department of Chemistry, Coimbatore – 641 043, Tamil Nadu, India
2. Arulmigu Palaniandavar College of Arts and Culture, Post Graduate and Research Department of Chemistry, Palani – 624 601, Tamil Nadu, India

Abstract

Hydrothermal carbonization is an environmentally friendly method that converts raw biomass into material resources of high value. In recent years scientists have been conducting concerted efforts to minimize food waste accumulation and pollution by turning towards biomass vapourisation. In the current global climate, it is a massive challenge to satisfy the demand for energy while also reducing the associated environmental degradation. Using biomass as a renewable energy source to combat these energy issues is becoming more and more relevant. In the present study, sesame oilcake and groundnut oilcake- vastly used as fodder for animal and considered waste, were converted into porous carbon  and the applicability of hydrochar carbon was ascertained using several characterization techniques, namely FTIR, SEM, proximate analysis, EDAX and TGA. The physical analysis inferred that the examined oil cakes contained lower carbon and oxygen content indicating high protein and energy contents. EDAX analysis of samples confirmed the applicability of produced hydrochars as nutritional supplements for plants.

Keywords

Hydrochar, Oilcake, Hydrothermal carbonization, Biomass, Sesame oilcake, Groundnut oilcake

References

  1. Omar, J. A. 2002. Effects of feeding different levels of sesame oil cake on performance and digestibility of Awassi lambs. Small Ruminant Res., 46(2-3): 187-190.
  2. Fernández-Cegrí, V., et al. 2012. Effect of hydrothermal pretreatment of sunflower oil cake on biomethane potential focusing on fibre composition. Bioresour. Tech., 123: 424-429.
  3. Roman, S., et al. 2012. Hydrothermal carbonization as an effective way of densifying the energy content of biomass. Fuel Processing Tech., 103: 78-83.
  4. Arami-Niya, A., et al. 2011. Optimization of synthesis and characterization of palm shell-based bio-char as a byproduct of bio-oil production process. BioResour., 7:246–264.
  5. Boocock, D.G.B. and K.M. Sherman. 1985. Further aspects of powdered poplar wood liquefaction by aqueous pyrolysis. Canadian J .Chem. Eng., 63:627-633.
  6. Hoekman, S. K., et al. 2013. Hydrothermal carbonization (HTC) of selected woody and herbaceous biomass feedstocks. Biomass Conversion Biorefi-nery. 3: 113-126.
  7. Sahitya, S., et al. 2017. Hydrogen-rich syngas from jatropha curcas shell biomass char in fresnel lens solar concentrator assembly. Energy Fuels. 31(8): 8335-8347.
  8. Qayyum, M. F., et al. 2015. Effects of various biochars on seed germination and carbon mineralization in an alkaline soil. Pakistan J. Agric. Sci., 51: 977-982.
  9. ASTM D5142. 2004. Standard test methods for proximate analysis of the analysis sample of coal and coke by instrumental procedures. ASTM International, West Conshohocken, PA, USA.
  10. ASTM D3172. 2021. Standard practice for proximate analysis of coal and coke. ASTM International, West Conshohocken, PA, USA.
  11. ASTM D4442. 2020. Standard test methods for direct moisture content measurement of wood and wood-based materials. ASTM International, West Conshohocken, PA, USA.
  12. ASTM E1755. 2001. Standard test method for ash in biomass. ASTM International, West Consho-hocken, PA, USA.
  13. Werther, J., et al. 2000. Combustion of agricultural residues. Prog. Energy Combust. Sci., 26:1-27.
  14. Ofori-Boateng, C. and K.T. Lee. 2013. The potential of using cocoa pod husks as green solid based catalysts for the transesterification for soybean oil into biodiesel: Effects of biodiesel on engine performance. Chem. Eng. J.,220: 395-401.
  15. Martins, A. and N. Nunes. 2015. Adsorption of a textile dye on commercial activated carbon: A simple experiment to explore the role of surface chemistry and ionic strength. J. Chem. Educ., 92(1):143-147.
  16. Rodríguez-Reinoso, F. and M. Molina-Sabio. 1992. Activated carbons from lignocellulosic materials bychemical and/ or physical activation: An overview. Carbon. 30(7): 1111–1118.
  17. Lapuerta, M.N., J.J. Hernandez and J.N. Rodríguez. 2004. Kinetics of devolatilisation of forestry wastes from thermogravimetric analysis. Biomass Bioenergy. 27:385–391.
  18. Li, B., et al. 2019. Adsorption of methylene blue and Cd(II) onto maleylated modified hydrochar from water. Env. Poll., 254: 113014.
  19. El-Sayed, S.A. and M.E. Mostafa. 2014. Pyrolysis characteristics and kinetic parameters determination of biomass fuel powders by differential thermal gravimetric analysis (TGA/DTG). Energy Conversion Manage., 85:165–172.
  20. Asadieraghi, M. and W.M.A. Wan Daud. 2014. Characterization of lignocellulosic biomass thermal degradation and physio-chemical structure: Effects of demineralization by diverse acid solutions. Energy Conversion Manage., 82:71–82.
  21. Trivedi, N. S., et al. 2016. Characterization and valorization of biomass ashes. Env. Sci. Poll. Res., 23: 20243-20256.