IJEP 45(7): 597-608 : Vol. 45 Issue. 7 (July 2025)
H.V. Srikanth1*, B.A. Praveena2, S. Balaji3, N. Santhosh4 and G.L. Arunkumar2
1. Nitte (Deemed to be University), Nitte Meenakshi Institute of Technology (NMIT), Department of Aeronau-tical Engineering, Bangalore – 560 064, Karnataka, India
2. Nitte (Deemed to be University), Nitte Meenakshi Institute of Technology (NMIT), Department of Mechanical Engineering, Bangalore – 560 064, Karnataka, India
3. REVA University, School of Mechanical Engineering, Bangalore – 560 064, Karnataka, India
4. MVJ College of Engineering, Department of Mechanical Engineering, Bangalore – 560 067, Karnataka, India
Abstract
In this study, the transesterification of castor seed oil for biodiesel production was significantly improved through the application of response surface methodology (RSM) and central composite design (CCD) and artificial neural network (ANN). The optimized conditions yielded an impressive biodiesel production efficiency of 98.3%. The key parameters influencing the process included a methanol-to-oil molar ratio (M:O) of 15:1, catalyst concentration (CC) of 4 wt.% (KOH), reaction temperature (RT) set at 55°C, and a reaction time (Rt) of 75 min. The quadratic model confirmed by ANOVA displayed robustness and reliability, with a highly significant p-value (<0.0001), indicating a strong correlation between biodiesel yield and the model variables. Also, the R2 values obtained from RSM and ANN were found to be 0.99 and 0.96, which indicates that the model developed was fit and satisfactory with the actual experimental values. The resulting biodiesel exhibited favorable fuel properties, endorsing its suitability for compression ignition (CI) engines. This optimization not only enhances biodiesel production efficiency but also underscores the pivotal role of statistical techniques in refining reaction parameters for superior biofuel quality and broader applicability.
Keywords
Castor seed oil, Response surface methodology, Central composite design, Transesterification, Optimization
References
- BP. 2020. Statistical review of world energy 2020 (69th edn). British Petroleum.
- Ntaribi, T. and D.I. Paul. 2019, The economic feasibility of Jatropha cultivation for biodiesel production in Rwanda: A case study of Kirehe district, Int. J. Sustain. Energy Develop., 50: 27-37. DOI: 10.1016/j.esd.2019.03.001.
- Thakur, A.K., et al. 2020. An overview of butanol as compression ignition engine fuel. Int. J. Energy Clean Env., 21(4): 333-354. DOI: 10.1615/InterJ EnerCleanEnv.2020033667.
- Sarkar, A., et al. 2021. Effects of ethanol as the renewable fuel blended with gasoline on the performance and emission characteristics of a small variable compression ratio spark-ignition engine. Int. J. Energy Clean Env., DOI: 10.1615/InterJEnerClean Env.2021038246.
- Srikanth, H.V., et al. 2021. Niger seed oil biodiesel as an emulsifier in diesel-ethanol blends for compression ignition engine. Renew. Energy. 163: 1-12. DOI: 10.1016/j.renene.2020.07.010.
- Miraculas, G.A., N. Bose and R.E. Raj. 2018. Process parameter optimization for biodiesel production from mixed feedstock using empirical model. Sustain. Energy Tech. Assessments. 28: 54–59. DOI: 10.1016/j.seta.2018.06.004.
- Ayoob, K.A. and A.B. Fadhil. 2020. Valourization of waste tires in the synthesis of an effective carbon-based catalyst for biodiesel production from a mixture of non-edible oils. Fuel. 264: 116754. DOI: 10.1016/j.fuel.2019.116754.
- Lapuerta, M., O. Armas and R. Garcia-Contreras. 2009. Effect of ethanol on blending stability and diesel engine emissions. Energy Fuels. 23: 4343-4354.
- Kwanchareon, P., A. Luengnaruemitchai and S. Jai-In. 2007. Solubility of a diesel-biodiesel-ethanol blend, its fuel properties and its emission characteristics from diesel engine. Fuel. 86: 1053-1061.
- Keera, S.T., S.M. El Sabagh and A.R. Taman. 2018. Castor oil biodiesel production and optimization. Egyptian J. Petroleum.27: 979–984. DOI: 10.1016/j.ejpe.2018.02.007.
- Bastante, J.S., et al. 2015. Synthesis of biodiesel from castor oil: Silent versus sonicated methylation and energy studies. Energy Conversion Manage., 96: 561-567. DOI: 10.1016/j.enconman.2015.03. 019.
- Canoira, L., et al. 2010. Fatty acid methyl esters (FAMEs) from castor oil: Production process asse-ssment and synergistic effects in its properties. Renew. Energy.35(1): 208-217. DOI: 10.1016/j.re nene.2009.05.006.
- Dias, J.M., et al. 2013. Biodiesel production from raw castor oil. Energy. 53: 58-66. DOI: 10.1016/j.energy.2013.02.018.
- Sánchez, N., et al. 2015. Biodiesel production from castor oil under subcritical methanol conditions. Int. J. Env. Sci. Develop.,6(1): 61-66.
- Baskar, G., and R. Aiswarya. 2016. Trends in catalytic production of biodiesel from various feedstocks. Renew. Sustain. Energy Reviews. 57: 496-504. DOI: 10.1016/j.rser.2015.12.101.
- Rani, D.S., V.B. Borugadda and V.V. Goud. 2016. Reactive extraction of castor seeds and storage stability characteristics of produced biodiesel. Process Safety Env. Prot., 100: 252-263. DOI: 10.101 6/j.psep.2016.01.019.
- Yesilyurt, M.K., et al. 2020. The production of biodiesel from safflower (Carthamus tinctoriusL.) oil as a potential feedstock and its usage in compression ignition engine: A comprehensive review. Renew. Sustain. Energy Reviews. 119: 109574. DOI: 10.1016/j.rser.2019.109574.
- Yesilyurt, M.K., M. Arslan and T. Eryilmaz. 2018. Application of response surface methodology for the optimization of biodiesel production from yellow mustard (Sinapis albaL.) seed oil. Int. J. Green Energy. 16(3): 1-12. DOI: 10.1080/15435075. 2018.1532431.
- Rajendran, N., et al. 2022. Process optimization, economic and environmental analysis of biodiesel production from food waste using a citrus fruit peel biochar catalyst. J. Clean. Prod., 365: 132712. DOI: 10.1016/j.jclepro.2022.132712.
- Witek-Krowiak, A., et al. 2014. Application of res-ponse surface methodology and artificial neural network methods in modelling and optimization of biosorption process. Bioresour. Tech., 160: 150-160.
- Dwivedi, G. and M.P. Sharma. 2015. Application of Box–Behnken design in optimization of biodiesel yield from Pongamia oil and its stability analysis. Fuel. 145: 256–262.
- Verma, P., M.P. Sharma and G. Dwivedi. 2016. Prospects of bio-based alcohols for Karanja biodiesel production: An optimization study by res-ponse surface methodology. Fuel. 183: 185–194.
- Sarve, A., M.N. Varma and S. Shriram. 2015. Optimization and kinetic studies on biodiesel production from kusum (Schleichera triguga) oil using res-ponse surface methodology. J. Japan Oil Chemists’ Soc., 64(9): 987-997. DOI: 10.5650/jos.ess15069.
- Raj, V.A., et al. 2021. Modelling and process optimization for biodiesel production from Nanno-chloropsis salina using artificial neural network. Bioresour. Tech., 329: 124872. DOI: 10.1016/j.biortech.2021.124872.
- Srikanth, H.V., et al. 2023. Production optimisation of mixed oil (rubber seed oil–fish oil) feedstock using response surface methodology and artificial neural network. Int. J. Ambient Energy. 44(1): 2336–2346. DOI: 10.1080/01430750.2023.223 61072023.
- ASTM D6751-15c. Standard specification for biodiesel fuel blend stock (B100) for middle distillate fuels. ASTM International.
- Omari, A., Q.A. Mgani and E.B. Mubofu. 2015. Fatty acid profile and physico-chemical parameters of castor oils in Tanzania. Green Sustain. Chem., 5(4): 154-163. DOI: 10.4236/gsc.2015.54019.
- Omohu, O.J. and A.C. Omale. 2017. Physico-chemical properties and fatty acid composition of castor bean Ricinus communis L. seed oil. European J. Biophys., 5(4): 62–65. DOI: 10.11648/j.ejb.2017 0504.11.
- Mostafaei, M., et al. 2015. Optimization of ultrasonic assisted continuous production of biodiesel using response surface methodology. Ultrasonics Sonochem., 27: 54–61.
- Kostic, M.D., et al. 2016. Optimization and kinetics of sunflower oil methanolysis catalyzed by calcium oxide-based catalyst derived from palm kernel shell biochar. Fuel. 163: 304–313.
- Ejikeme, P.M., et al. 2010. Catalysis in biodiesel production by transesterification processes—An insight. J. Chem., 7: 1120–1132.
- Atapour, M., H.R. Kariminia and P.M. Moslehabadi. 2014. Optimization of biodiesel production by alkali-catalyzed transesterification of used frying oil. Process Safety Env., 92(2): 179-185.
- Olutoye, M.A. and B.H. Hameed. 2009. KyMg1-x Zn1+xO3as a heterogeneous catalyst in the trans-esterification of palm oil to fatty acid methyl esters. Appl. Catalysis A: General. 371: 191–198.
- Hsaio, M.C., et al. 2010. Ultrasonic mixing and closed microwave irradiation assisted transesterifi-cation of soybean oil. Fuel. 89: 1641–1644.
- Sivamani, S., et al. 2019. Artificial neural network–genetic algorithm-based optimization of biodiesel production from Simarouba glauca. Biofuels. 10 (3): 393–401. DOI: 10.1080/17597269.2018.1432 267.
- Garg, A. and S. Jain. 2020. Process parameter optimization of biodiesel production from algal oil by response surface methodology and artificial neural networks. Fuel. 277: 118254. DOI: 10.1016/j.fu el.2020.118254.
- Ayoola, A.A., et al. 2019. Impact assessment of biodiesel production using CaO catalyst obtained from two different sources. Cogent Eng.,6(1). DOI: 10.1080/23311916.2019.1615198.
- Giordano, P.C., et al. 2010. Application of response surface methodology and artificial neural networks for optimization of recombinant Oryza sativa non-symbiotic hemoglobin 1 production by Escherichia coli in medium containing byproduct glycerol. Bioresour. Tech., 101 (19): 7537–7544. DOI: 10.1016/j.biortech.2010.05.001.
- Bahramik, N. 2014. Effects of planting pattern on yield, its components, oil contain and some important agronomic traits of safflower (Carthamus tinctorius L.) in dry land conditions. Int. J. Agric. Crop Sci., 4(2): 86-91.
- Ilkiliç, C., et al. 2011. Biodiesel from safflower oil and its application in a diesel engine. Fuel Processing Tech., 92(3): 356-362. DOI: 10.1016/j.fup roc.2010.09.028.
- Hamamci, C., et al. 2011. Biodiesel production via transesterification from safflower (Carthamus tinctoriusL.) seed oil. Energy Sources, Part A: Recovery, Utilization Env. Effects. 33(6): 512-520. DOI: 10.1080/15567030903096964.
- Indiastat, R.M. 2012. Effects of plant population on growth, development and oil yield of safflower. J. Agric. Sci. Tech., 3: 321-333.
- Mumtaz, M.W., et al. 2014. RSM based optimization of chemical and enzymatic transesterification of palm oil: Biodiesel production and assessment of exhaust emission levels. Sci. World J., 11. DOI: 10.1155/2014/526105.
- Onukwuli, D.O., et al. 2017. Optimization of biodiesel production from refined cotton seed oil and its characterization. Egypt J. Pet., 26: 103–110.
- Babu, R. and S. Godiganur. 2015. Safflower seed (Guizotia abyssinica) as a source of biodiesel in India. Int. J. Eng. Res. Tech., 3 (17).
- Renita, A.A., J.D. Amarnath and S.A. Sivasubra-manian. 2012. Study on the optimization of algal biodiesel reaction parameters using response surface methodology. Int. J. Chem. Eng. Appl., 3(5): 311-314.
- Sibanda, W. and P. Pretorius. 2013. Comparative study of the application of central composite face-centred (CCF) and Box-Behnken designs (BBD) to study the effect of demographic characteristics on HIV risk in South Africa. Netw. Model Anal. Health Infor. Bioinfor., 2: 137–146.
- Silva, G.F., F.L. Camargo and A.L.O. Ferreira. 2011. Application of response surface methodology for optimization of biodiesel production by transesteri-fication of soybean oil with ethanol. Fuel Process Tech., 92: 407–413.
- Singh, B. 2012. Synthesis of biodiesel using potassium fluoride (KF) supported by hydrotalcite and process optimization by Box-Behnken design. Biomass Conv. Bioref., 2: 317–325.