IJEP 41(6): 673-680 : Vol. 41 Issue. 6 (June 2021)
1. National Polytechnic School, Laboratory of Materials (LABMAT), EL Menaouer, Oran, Algeria
2. Relizane University Center, Department of Civil Engineering, Algeria
3. Ecole Nationale Polytechnique Maurice Audin, Laboratory of Micro and Nanophysics (LaMiN), Department of Physics, El M’Naouer, 31000, Oran, Algeria
Abstract
In the present work, study of the adsorption of the yellow dye G (azo type) which is found in the discharges of a textile factory ENADITEX of the industrial zone of wilaya of Oran, Algeria on pozzolana which is a natural and easily available adsorbent was conducted. Experimental results showed that the adsorption of the yellow dye G on pozzolana showed a removal rate of 78.80% for a maximum time of 60 min at initial pH (13.09) and room temperature. The study of isotherms revealed that both Freundlich and Temkin models fit well with the process of dye adsorption. The kinetic data were modelled by the pseudo-first order and pseudo-second order equations and reveal that the adsorption of the yellow dye G is governed by the second order kinetic model. The thermodynamic study indicates that the adsorption process is of spontaneous physical and endothermic nature.
Keywords
Natural pozzolana, Yellow dye G, Adsorption isotherms, Kinetics study, Thermodynamic study
References
- Khan, A. J., et al. 2020. Mesoporous silica MCM-41, SBA-15 and derived bridged polysilsesquioxane SBA-PMDA for the selective removal of textile reactive dyes from wastewater. J. Molecular Liquids. 298.
- Rehman, F., A. Rahim and C. Airoldi. 2016. Preparation and characterization of glycidyl-methacry-lateorgano bridges grafted mesoporous silica SBA-15 as ibuprofen and mesalamine carrier for controlled release. Mater. Sci. Eng., 59: 970-979.
- Carmen, Z. and S. Daniela. 2012. Textile organic dyes – Characteristics, polluting effects and separation/elimination procedures from industrial effluents – A critical overview. Organic pollutants ten years after the Stockholm convention – Environmental and analytical update. DOI: 10.5772/32373.
- Natali, F., et al. 2011. Removal of Remazol Black B textile dye from aqueous solution by adsorption. Desalination. 269: 92-103.
- Shirazi, E., et al. 2020. Removal of textile dyes from single and binary component systems by Persian bentonite and a mixed adsorbent of bentonite/charred dolomite. Colloids Surfaces A: Physico-chem. Eng. Aspects. 598.
- Aditya, S., et al. 2019. Adsorption of textile wastewater on alkali – Activated sand. J. Cleaner Production. 220: 23-32.
- Nidheesh, P. V., et al. 2018. An overview on the removal of synthetic dyes from water by electrochemical advanced oxidation processes. Chemosphere. 197: 210-227.
- Lemlikchi, W., et al. 2015. Kinetic study of the adsorption of textile dyes on synthetic hydroxyapatite in aqueous solution. J. Ind. Eng. Chem., 32: 233-237.
- Li, C., et al. 2018. Facile synthesis of low cost magnetic biosorbent from peach gum polysaccharide for selective and efficient removal of cationic dyes. Int. J. Biol. Macromol., 107: 1871-1878.
- Hala, R., S. M. Ibrahim and A. Sahar. 2016. Textile dye removal from aqueous solutions using cheap MgO nanomaterials: Adsorption kinetics, isotherm studies and thermodynamics. Adv. Powder Tech., 27: 223-231.
- Wang, X., et al. 2018. Carbon composite lignin based adsorbents for the adsorption of dyes. Chemosphere. 206: 587-596.
- Lian, L., L. Guo and C. Guo. 2009. Adsorption of Congo Red from aqueous solutions onto Ca-bentonite. J. Hazard. Mater., 161: 126-139.
- Dil, E. A., et al. 2019. Efficient adsorption of Azure B onto CNTs/Zn: ZnONi2P-NCs from aqueous solution in the presence of ultrasound wave based on multivariate optimization. J. Ind. Eng. Chem., 74: 55-62.
- Naushad, M., et al. 2015. Ion-exchange kinetic studies for Cd(II), Co(II), Cu(II) and Pb(II) metal ions over a composite cation exchanger. Desalin. Water Treat., 54: 2883-2890.
- Lemlikchi, W., et al. 2015. Kinetic study of the adsorption of textile dyes on synthetic hydroxyapatite in aqueous solution. J. Ind. Eng. Chem., 32: 233-237.
- Rijo, R., et al. 2019. Adsorption of textile dyes with ultrasonic assistance using green reduced graphene oxide: An in-depth investigation on sonochemical factors. J. Env. Chem. Eng., 7(6).
- Nezampour, F., M. Ghiaci and K. Masoomi. 2018. Activated carbon and graphitic carbon nitride immobilized on mesoporous silica for adsorption of nitrobenzene. J. Chem. Eng., 63: 1977-1986.
- Meghmik, M., T. Hossein and H. Fashandi. 2018. Synthesis of highly uniform m-sulphur doped carbon sphere using CVD method and its application for cationic dye removal in comparison with undoped product. J. Env. Chem. Eng., 6: 6904-6915.
- Sara, Y., et al. 2016. Cobalt ferrite nanoparticles: Preparation, characterization and anionic dye removal capability. J. Taiwan Institute Chem. Engineers. 59: 320-329.
- Jafar, A., et al. 2016. Synthesis of metal organic framework hybrid nanocomposites based on GO and CNT with high adsorption capacity for dye removal. Chem. Eng. J., 326: 1145-1158.
- Kamaraj, R., et al. 2019. Facile one pot electrosynthesis of zinc hydroxide for the adsorption of hazardous 2-(2-methyl-4-chlorophenoxy) propionic acid (MCPP) from water and its modelling studies. J. Env. Chem. Eng., 6: 2017-2026.
- Saeed, P. G., et al. 2020. Comprehensive monolayer two parameter isotherm and kinetic studies of thiamine adsorption on clay minerals: Experimental and modeling approaches. J. Molecular Liquids. 306.
- Huang, Y. D. 2019. Comments on using of pseudo-first-order model. Appl. Surface Sci., 469: 564-565.
- Ru, L. T., et al. 2014. A convenient method to determine kinetic parameters of adsorption processes by nonlinear regression of pseudo-nth-order equation. Chem. Eng. J., 237: 153-161.
- Mi, X., et al. 2020. A double layered neutral cadmium organic framework for selective adsorption of cationic organic dyes through electrostatic affinity. J. Solid State Chem., 288.
- Changquan, H., et al. 2019. Synthesis of spherical magnetic calcium modified chitosan micro-particles with excellent adsorption performance for anionic-cationic dyes. Int. J. Biol. Macromolecules. 128: 593-602.
- Gupta, V., et al. 2020. Sequestration of toxic Congo Red dye from aqueous solution using eco-friendly guar gum/activated carbon nanocomposite. Int. J. Biol. Macromolecules. 158: 1310-1318.
- Ying, Z., et al. 2016. Superior adsorption capacity of Fe3O4@nSiO2@mSiO2core shell microspheres for removal of Congo Red from aqueous solution. J. Molecular Liquids. 219: 88-94.
- Wu, S. H., C. Y. Mou and H. P. Lin. 2013. Synthesis of mesoporous silica nanoparticles. Chem. Soc. Rev., 42: 3862-3875.
