Toward Green Concrete: Replacing Clinker with Trass materials to Produce Portland Pozzolan Cement

IJEP 43(5): 452-458 : Vol. 43 Issue. 5 (May 2023)

Herliati Rahman* and Alvian Maulana

Jayabaya University, Department of Chemical Engineering, Faculty of Industrial Technology, Cimanggis Jakarta Timur, Indonesia

Abstract

Trass is a pozzolanic additive from soft rock or soil layers derived from volcanic ash. This component can replace clinker in the manufacture of cement. The advantages of trass in cement manufacture are that it can regulate the reaction of calcium hydrate cement, increase chemical stability and improve mechanical properties. This study investigates the effect of adding trass to the quality of Portland pozzolan cement (PPC) in terms of compressive strength and setting time. In addition, it also observed the chemical and physical properties of cement. During the study, the substitution of trass on the clinker was in the range of 0-40% of the total mass. In addition, gypsum and limestone compositions were set at 3% and 5%, respectively. In other words, clinker was added at a variation of 52 to 86% (w/w). In this study, the fineness factor of the cement mixture was maintained in the range of 3800 – 4000 cm2/g. The effect of the contribution of trass on the cement mixture was measured by testing the chemical and physical properties, the compressive strength test of the mortar and the setting time test at the age of 1, 3, 7 and 28 days. The results showed that the addition of 21% trass significantly increased the mechanical properties of PPC at the age of 28 days, where the compressive strength was 371 kg/cm2, the initial setting time was 190 min and the maximum final setting time was 290 min.

Keywords

Additives, Clinker ratio, Composite, Compressive strength

References

  1. Irawan, R.R. 2013. Portland cement in Indonesia for high performance concrete applications (1st edn). Indonesian Ministry of Public Works, Jakarta.
  2. Ircham, M. 2018. ASI report: Consumption of cement in Indonesia 2017. Indonesian Cement Association, Jakarta, Indonesia.
  3. Tasci, E., et al. 2004. The effects of addition two different types of trass to the clinkering reaction. Gazi University J. Sci., 22 (1):701-708.
  4. Holgard, D. and J. Sundkvist. 2020. Climate enhanced concrete in the civil engineering industry. Ph.D. Thesis. KTH Royal Institute of Technology, Sweden.
  5. Kapelusznal, E., et al. 2021. Implementation of alternative mineral additives in low-emission sustainable cement composites. Mater., 14(21):1-21.
  6. Kapelusznal, E., et al. 2020. The effect of highly reactive pozzolanic material on the early hydration of alite-C3A-gypsum synthetic cement systems. Construction Building Mater., 251(1):118879.
  7. Rahman, H., D.P. Asha and L. Nulhakim. 2020. Clinker ratio optimization in Portland pozzoland cement (PPC) with pozzoland flyash. J. Migasian Akamigas Balongan Indramayu. 4(2):1-9. DOI: 10.36601/jurnal-migasian.v4i2.126.
  8. Shehata, N., et al. 2022. Recent progress in environmentally friendly geopolymers : A review. European J. Env. Civil Eng., 762(5): 143166.
  9. Ibrahim, S. and A. Meawad. 2022. Towards green concrete : Study the role of waste glass powder on cement/superplasticizer compatibility. J. Building Eng., 47(1).
  10. Monika, F., et al. 2022. Engineering properties of concrete made with coal bottom ash as sustainable construction materials. Civil Eng. J., 8(1):181-194.
  11. Cicek, B., et al. 2020. A reverse engineering approach for low environmental impact earth stabilization technique. IOP Conf. Series Earth Env. Sci., 588:1.11-1.14.
  12. Ghasemi, A., et al. 2022. Evaluation of the phase composition, microstructure, mechanical performance and resistance to acid attack of blended cement paste composed of binary trass-cement system. Construction Building Mater., 333(c): 127356.
  13. Singh, S.B., N. Thammishetti and P. Munjal. 2015. Role of water cement ratio on the cement mortar. J. Building Eng., 4(1): 94-100.
  14. Kazemian, M.S.A.R. and F. Bahman-Zadeh. 2021. Effects of cyclic carbonation and chloride ingress on durability properties of mortars containing trass and pumice natural pozzolans. Structural Concrete. 22(5):2704-2719.
  15. Vijaya, S.K., K. Jagadeeswari and K. Srinivas. 2021. Behaviour of M60 grade concrete by partial replacement of cement with flyash, rice husk and silica fume. Mater. Today. 37(2):2104-2108.
  16. Herliati, et al. 2021. Optimization of gypsum composition against setting time and compressive strength in clinker for PCC (Portland composite cement). IOP Conf. Series Mater. Sci. Eng., 1053 (1): 012116.
  17. Joshaghani, A. 2017. The effect of trass and flyash in minimizing alkali-carbonate reaction in concrete. Construction Building Mater., 105(1):583-590.
  18. Zhang, D., et al. 2022. Effect of equal volume replacement of fine aggregate with flyash on carbonation resistance of concrete. Mater., 15(4).
  19. Joshaghan, A., et al. 2017. Experimental study of the use of trass as a supplementary cementitious material in pervious concrete. J. Env. Sci. Eng., 8(2):39-52.
  20. Ustabas, I., et al. 2021. Pozzolanic effect on the hydration heat of cement incorporating flyash, obsidian and slag additives. Adv. Civil Eng., 2021 (6):1-12.
  21. Susanti, N., S.M. Sari and E. Maulana. 2019. A study of strength activity index of pozzolan and silica sand with ordinary portland cement using ASTM C595/C595M-12 method. J. Technomater. Physics. 1(2):148-155.
  22. ASTM. 2008. Annual book of ASTM standard section. American Standard for Testing Material, Philadelphia.
  23. Mardani, A., et al. 2017. Effect of cement fineness on properties of cementitious materials containing high range water reducing admixture. J. Green Building. 12(1):142-167.
  24. Amhudo, R.L., et al. 2018. Comparison of compressive and tensile strengths of dry-cast concrete with ordinary portland and portland pozzolana cements. Civil Eng. J., 4(8):1760-1771.
  25. Tang, L.V., et al. 2018. Effect of rice husk ash and flyash on the workability of concrete mixture in the high rise construction. E3S Web Conf., 33: 02029.
  26. Sunarno, Y., et al. 2020. Preliminary study on early compressive strength of foam concrete using ordinary portland cement (OPC) and portland composite cement (PCC). IOP Conf. Series Earth Env. Sci., 419(1): 012033.
  27. Priastiwi, Y.A., et al. 2022. Effect of trass substitution in sand on the compressive and flexure strength of concrete. IOP Conf. Series Earth Env. Sci., 969(1): 012076.
  28. Waani, J., S. Prabandiyani and B.H. Setiadji. 2014. Effect of natural pozzolan substitution (tras) on cement on compressive strength. J. Media Komunikasi Teknik Sipil. 20(1):43-52. DOI: 10.147 10/mkts.v20i1.9245.
  29. Arigin, G. and B. Uzal. 2021. Enhancement of pozzolanic activity of calcined clays by limestone powder addition. Construction Building Mater., 284(1): 1-11.